JEE Advanced levelSingle correct optionDifficulty 3 of 3pl153
Terylene (repeat unit CX10HX8OX4, 192) of mass 960 g is made by the dimethyl terephthalate route from dimethyl terephthalate and ethylene glycol (end groups ignored; CHX3OH = 32). The mass of methanol released in grams is
A320
B160
C640
D180
Answer: A
960 g corresponds to 960/192=5.00 repeat units (mol). Each repeat unit forms two ester links by exchange of two −OCHX3 groups, so 10.0 mol of methanol is released. Mass =10.0×32=320 g; the value 180 g would be water.