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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl154

Which monomer combination gives a linear, thermoplastic condensation polymer rather than a cross-linked network?

  1. AMelamine and formaldehyde
  2. BGlycerol (propane-1,2,3-triol) and phthalic acid
  3. CEthylene glycol and terephthalic acid
  4. DPhenol and formaldehyde

Answer: C

A linear chain needs two bifunctional monomers. Ethylene glycol and terephthalic acid are each bifunctional. Phenol (three reactive ring positions), melamine (three amino groups) and glycerol (three hydroxyl groups) have functionality above two, so they give branched or network polymers.
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