JEE Main levelNumerical answerDifficulty 2 of 3pt205
Pauling's relation is χB−χA=Δ, where Δ=E(A−B)−E(A−A)E(B−B) is expressed in eV. The bond energies of a hypothetical pair are E(A−A)=190, E(B−B)=250 and E(A−B)=300 kJ/mol. Using 1eV=96.5 kJ/mol, calculate χB−χA (answer to two decimal places).
Numerical answer type, tolerance 0.02.
Answer: 0.92
The geometric mean is 190×250=217.94 kJ/mol, so Δ=300−217.94=82.06 kJ/mol. In eV this is 82.06/96.5=0.850 eV. Then χB−χA=0.850=0.92.