JEE Advanced levelSingle correct optionDifficulty 3 of 3pt211
Allred-Rochow electronegativity is given by χ=0.359Zeff/r2+0.744 with r in angstrom. For an element with Zeff=5.45 and covalent radius 1.10 angstrom, the value of χ is nearest to
A2.36
B2.52
C1.62
D4.46
Answer: A
r2=1.21, so 0.359×5.45/1.21=1.617. Adding 0.744 gives 2.36. The value 2.52 comes from forgetting to square r, 1.62 from omitting the constant, and 4.46 from multiplying by r2 instead of dividing.