JEE Advanced levelSingle correct optionDifficulty 3 of 3pt162
Element A has ΔiH1=496 and ΔiH2=4562kJmol−1. Element Z (period 3) has a first electron gain enthalpy of −200kJmol−1 and a very positive second value. The most probable formula of the ionic compound formed between them is
AAZX2
BAX2Z
CAX2ZX3
DAZ
Answer: B
The huge ΔiH2 shows A has one valence electron and forms AX+ (Na). Z needs two electrons to reach octet (S). Charge balance gives AX2Z, i.e. NaX2S.