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JEE Advanced levelSingle correct optionDifficulty 3 of 3pt159

Down group 17 the electron gain enthalpy generally becomes less negative ( -349, -325, -295), yet (-328) is less negative than . Which statement correctly accounts for this?

  1. AFluorine has a larger atomic radius than chlorine, so it holds the extra electron weakly
  2. BThe very small subshell of gives strong inter-electronic repulsion that offsets its smaller size and stronger nuclear attraction
  3. CFluorine has a half-filled subshell, so it resists gaining an electron
  4. DFluorine has a lower nuclear charge than chlorine, so its attraction for the extra electron is smaller

Answer: B

Attraction for the added electron falls with size down the group, so Cl > Br > I. In F the incoming electron enters a tiny subshell already holding five electrons, and the repulsion lowers the energy released. F has a smaller (not larger) radius and a higher-than-chlorine attraction per unit distance, and its subshell is , not half-filled.
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