JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pt165
Let EA be the electron affinity (energy released on forming XX− from X, ignoring the small RT correction). Given that the electron gain enthalpies are F−328, Cl−349, Br−325, I−295kJmol−1, select the correct statements.
AThe energy needed to remove an electron from ClX− is 349kJmol−1
BClX− is harder to ionise than FX−
CIX− is easier to ionise than BrX−
DThe energy needed to remove an electron from FX− is −328kJmol−1
Answer: A, B, C
Ionising XX− reverses electron gain, so it costs +|EGE|: Cl- 349, F- 328, Br- 325, I- 295. So Cl- > F- and I- < Br-. Removal of an electron from F- cannot be exothermic (-328), so the last statement is false.