JEE Advanced levelSingle correct optionDifficulty 3 of 3pt160
Electron gain enthalpy of Cl is −349kJmol−1. Take 1 eV per atom = 96.5kJmol−1 and hc=1240eVnm. The longest wavelength of light that can detach an electron from ClX−(g) is closest to
A171nm
B343nm
C686nm
D3.5nm
Answer: B
Detaching the electron needs +349 kJ/mol = 349/96.5 = 3.62 eV per ion. Wavelength = 1240/3.62 = 343 nm. Halving or doubling the energy gives 686 or 171 nm.