JEE Main levelSingle correct optionDifficulty 2 of 3pt125
Gallium has a slightly higher first ionisation enthalpy (579kJmol−1) than aluminium (577kJmol−1), contrary to the usual group trend. This is mainly because
Athe ten 3d electrons of Ga shield the nuclear charge poorly, so the effective nuclear charge on the 4p electron is higher than expected
BAl has a 3d subshell that is completely filled
CGa has a half-filled 4p subshell
DGa has a smaller number of shells than Al
Answer: A
Between Al and Ga the ten 3d electrons are added. Being diffuse, they screen the extra nuclear charge (+18) poorly, so Zeff rises and the atomic size does not grow much. This offsets the extra shell and IE1 is marginally higher for Ga.