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JEE Main levelSingle correct optionDifficulty 2 of 3pt125

Gallium has a slightly higher first ionisation enthalpy () than aluminium (), contrary to the usual group trend. This is mainly because

  1. Athe ten electrons of shield the nuclear charge poorly, so the effective nuclear charge on the electron is higher than expected
  2. B has a subshell that is completely filled
  3. C has a half-filled subshell
  4. D has a smaller number of shells than

Answer: A

Between Al and Ga the ten electrons are added. Being diffuse, they screen the extra nuclear charge () poorly, so Zeff rises and the atomic size does not grow much. This offsets the extra shell and IE1 is marginally higher for Ga.
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