JEE Main levelSingle correct optionDifficulty 2 of 3pt123
Sulfur has a slightly lower first ionisation enthalpy (1000kJmol−1) than phosphorus (1012kJmol−1). The best explanation is that
AP has a completely filled 3p subshell
Bin S (3p4) the electron removed comes from a paired orbital, and its loss relieves repulsion and leaves the stable half-filled 3p3 ion
CS has a lower nuclear charge than P
DS has a smaller atomic radius than P
Answer: B
P is 3p3 (half-filled, extra stable). Sulfur's fourth 3p electron shares an orbital and feels pair repulsion; removing it gives the half-filled SX+. So S is easier to ionise despite its higher nuclear charge.