NEET levelSingle correct optionDifficulty 1 of 3pt121
The second electron gain enthalpy of oxygen, for OX−(g)+e−→OX2−(g), is positive because
AOX− has a noble gas configuration
Boxygen has a half-filled 2p subshell
Can electron is being added to an already negatively charged ion and repulsion must be overcome
Doxygen has a very low nuclear charge
Answer: C
OX− is 2s22p5, and the new electron is repelled by the net negative charge. This repulsion outweighs the attraction of the nucleus, so the step is endothermic (about +744kJmol−1).