JEE Advanced levelSingle correct optionDifficulty 3 of 3pt105
Ionic potential is defined as ϕ=z/r (charge over radius in pm). Radii (6-coordinate, pm): BeX2+ 45, LiX+ 76, MgX2+ 72, CaX2+ 100 and AlX3+ 53.5. Which ion has an ionic potential closest to that of BeX2+?
ALiX+
BAlX3+
CMgX2+
DCaX2+
Answer: B
Values of 1000z/r: Be 44.4, Al 56.1, Mg 27.8, Ca 20.0, Li 13.2. Differences from Be: Al 11.6, Mg 16.7, Ca 24.4, Li 31.3. Al is closest, in line with the diagonal relationship of Be and Al.