JEE Advanced levelSingle correct optionDifficulty 3 of 3pt106
The metallic radii of Group 13 are Ga 135 pm, In 167 pm and Tl 170 pm. The increase from Ga to In is 32 pm but from In to Tl only 3 pm. The most appropriate explanation for the small second increase is:
ATl has the same number of shells as In
Bthe inert pair effect shortens the Tl−Tl metallic bond only
Cthe filled 4f (and 5d) subshells inserted before Tl shield the nucleus poorly, so Zeff is high and cancels most of the effect of the additional shell
DTl atoms lose the 6p electron and become cations in the metal
Answer: C
From In to Tl one shell is added, but 4f145d10 are filled in between. These shield poorly (lanthanoid contraction plus d-block contraction), raising Zeff, so the radius rises by only 3 pm against 32 pm for Ga to In.