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JEE Advanced levelSingle correct optionDifficulty 3 of 3pt106

The metallic radii of Group 13 are 135 pm, 167 pm and 170 pm. The increase from to is 32 pm but from to only 3 pm. The most appropriate explanation for the small second increase is:

  1. ATl has the same number of shells as In
  2. Bthe inert pair effect shortens the metallic bond only
  3. Cthe filled (and ) subshells inserted before Tl shield the nucleus poorly, so is high and cancels most of the effect of the additional shell
  4. DTl atoms lose the electron and become cations in the metal

Answer: C

From In to Tl one shell is added, but are filled in between. These shield poorly (lanthanoid contraction plus -block contraction), raising , so the radius rises by only pm against pm for Ga to In.
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