JEE Advanced levelSingle correct optionDifficulty 3 of 3pt102
Four ions W, X, Y and Z are the ions OX2−, FX−, NaX+ and MgX2+ in some order. Their 6-coordinate radii are W 72 pm, X 140 pm, Y 102 pm and Z 133 pm. The sum of the atomic numbers of W and Y is:
A20
B23
C21
D17
Answer: B
For isoelectronic ions radius falls as Z rises. The order X(140)>Z(133)>Y(102)>W(72) matches OX2−,FX−,NaX+,MgX2+. So W is Mg (12) and Y is Na (11); the sum is 23.