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JEE Advanced levelSingle correct optionDifficulty 3 of 3ph047

Bleaching powder, , releases chlorine on treatment with dilute acid. This happens because

  1. A disproportionates to and
  2. Bthe acid oxidises and separately to
  3. C (+1) and (-1) react to give (0) in a comproportionation
  4. D is reduced to only, and the acid is oxidised

Answer: C

In acid, . Chlorine at +1 is reduced to 0 and chlorine at -1 is oxidised to 0, so both pathways converge to . It is the reverse of the disproportionation of in alkali.
Practice p-Block Elements: Groups 17 and 18 More on Halogen compounds: HX, oxoacids, bleaching powder

More questions on Halogen compounds: HX, oxoacids, bleaching powder