JEE Advanced levelSingle correct optionDifficulty 3 of 3ph047
Bleaching powder, Ca(OCl)Cl, releases chlorine on treatment with dilute acid. This happens because
AOClX− disproportionates to ClX2 and OX2
Bthe acid oxidises ClX− and OClX− separately to ClX2
COClX− (+1) and ClX− (-1) react to give ClX2 (0) in a comproportionation
DOClX− is reduced to ClX− only, and the acid is oxidised
Answer: C
In acid, OClX−+ClX−+2HX+→ClX2+HX2O. Chlorine at +1 is reduced to 0 and chlorine at -1 is oxidised to 0, so both pathways converge to ClX2. It is the reverse of the disproportionation of ClX2 in alkali.