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JEE Advanced levelSingle correct optionDifficulty 3 of 3ph042

Using Lewis structures with Cl=O double bonds and no charge separation, the total number of lone pairs on all atoms (Cl and O) in the four molecules , , and taken together is

  1. A28
  2. B24
  3. C22
  4. D26

Answer: D

Count lone pairs on Cl from 7 valence electrons less the electrons used in bonds, and 2 on each terminal O and 2 on O of OH. HOCl: Cl 3 + O 2 = 5; HClO2: Cl 2 + OH 2 + O 2 = 6; HClO3: Cl 1 + OH 2 + 4 = 7; HClO4: Cl 0 + OH 2 + 6 = 8. The total is 26.
Practice p-Block Elements: Groups 17 and 18 More on Halogen compounds: HX, oxoacids, bleaching powder

More questions on Halogen compounds: HX, oxoacids, bleaching powder