JEE Advanced levelSingle correct optionDifficulty 3 of 3pn031
Zinc reacts with dilute nitric acid to give Zn(NOX3)X2, NX2O and water. After balancing the equation by the electron-change method, the percentage of the nitric acid consumed that acts as the oxidising agent (i.e. is reduced) is
A10%
B40%
C50%
D20%
Answer: D
ZnZnX2+ gives 2 e−; 2NX+5NX2X+1O takes 8 e−. So 4Zn per NX2O: 4Zn+10HNOX34Zn(NOX3)X2+NX2O+5HX2O. Of 10 HNOX3, 2 are reduced to NX2O and 8 stay as nitrate, so the fraction reduced = 2/10=20%.