JEE Main levelNumerical answerDifficulty 2 of 3pn029
Excess NaOH solution is boiled with 6.60g of ammonium sulphate, (NHX4)X2SOX4 (atomic masses: H 1, N 14, O 16, S 32). Only 75% of the ammonia formed is collected. Taking the molar volume at STP as 22.4Lmol−1, calculate the volume of ammonia collected at STP in litres (give the answer to two decimal places).
Numerical answer type, answer in L, tolerance 0.01.
Answer: 1.68 L
(NHX4)X2SOX4+2NaOHNaX2SOX4+2NHX3+2HX2O. Molar mass = 132, so moles = 6.60/132=0.050, giving 0.100 mol NHX3. Collected = 0.100×0.75=0.0750 mol, volume = 0.0750×22.4=1.68L.