JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pn034
Which of the following statements about nitric acid are correct?
ACopper reacts with concentrated HNOX3 mainly to give NO.
BConcentrated HNOX3 oxidises iodine to iodic acid, HIOX3.
CGold dissolves in concentrated HNOX3 alone.
DThe yellow-brown colour of old concentrated HNOX3 is due to dissolved NOX2 formed by its decomposition in light.
Answer: B, D
IX2+10HNOX32HIOX3+10NOX2+4HX2O. Gold needs aqua regia (conc. HNOX3 : conc. HCl = 1:3). 4HNOX34NOX2+OX2+2HX2O on exposure to light gives the yellow-brown colour. Copper gives mainly NOX2 with the concentrated acid, and NO with the dilute acid. Correct: A, C.