JEE Advanced levelSingle correct optionDifficulty 3 of 3pb089
Silicon is made by heating silica with coke: SiOX2+2CSi+2CO. If 30.0 g of SiOX2 (molar mass 60 g/mol) is heated with excess coke and the yield of Si is 80%, the volume of CO produced at STP (22.4 L/mol) is
A8.96 L
B22.40 L
C17.92 L
D35.84 L
Answer: C
n(SiOX2)=30.0/60=0.50 mol. At 80% yield, n(Si)=0.40 mol, and 2 mol CO form per mol of Si, so n(CO)=0.80 mol. Volume =0.80×22.4=17.92 L.