JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pb088
Which of the following statements about silicon carbide (carborundum) and related compounds are correct?
ASiC is made by heating SiOX2 with excess coke at about 2000 to 3000 K in an electric furnace.
BSiC has a diamond-like three-dimensional covalent structure and is very hard.
CGlass is made by fusing SiOX2 with NaX2COX3, with evolution of COX2.
DIn SiC, carbon is in the +4 oxidation state.
Answer: A, B, C
SiOX2+3CSiC+2CO occurs at very high temperature. Each atom in SiC is tetrahedrally bonded, as in diamond, so it is a hard abrasive. Fusing sand with soda ash gives sodium silicate: SiOX2+NaX2COX3NaX2SiOX3+COX2. Carbon is more electronegative than silicon, so carbon is −4 and silicon +4 in SiC. Statements 1, 2 and 3 are correct.