JEE Advanced levelSingle correct optionDifficulty 3 of 3pb086
The cyclic silicate anion SiX6OX18X12− is built from six SiOX4 tetrahedra, each sharing two oxygens with its neighbours. The number of non-bridging (terminal) oxygen atoms in the ring is
A24
B18
C12
D6
Answer: C
Six tetrahedra each sharing two corners give 6×2/2=6 bridging oxygens (each shared by two Si). Terminal oxygens =18−6=12. Check: charge =6(+4)−2(18)=−12, as expected.