JEE Advanced levelSingle correct optionDifficulty 3 of 3pb087
A double-chain (band) silicate has the repeating anion SiX4OX11X6−. The number of oxygen atoms in the unit that are shared between two tetrahedra (bridging oxygens) is
A7
B4
C5
D6
Answer: C
Four tetrahedra have 4×4=16 oxygen corners. If b oxygens are shared, each counts for two corners, so the number of distinct oxygens is 16−b=11, giving b=5. Check: charge =4(+4)−2(11)=−6.