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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3o1104

Which of the following form a crystalline addition product with saturated aqueous sodium hydrogen sulphite under the usual textbook conditions (aldehydes, methyl ketones and unhindered cyclic ketones)?

  1. Abenzophenone,
  2. Bpropanal
  3. Cacetophenone,
  4. Dbutan-2-one

Answer: B, D

Propanal is an aldehyde and butan-2-one is a methyl ketone, so both add bisulphite. Acetophenone and benzophenone are conjugated and sterically hindered by phenyl groups, so they give no appreciable adduct.
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