JEE Advanced levelOne or more correct optionsDifficulty 3 of 3o1104
Which of the following form a crystalline addition product with saturated aqueous sodium hydrogen sulphite under the usual textbook conditions (aldehydes, methyl ketones and unhindered cyclic ketones)?
Abenzophenone, (CX6HX5)X2C=O
Bpropanal
Cacetophenone, CX6HX5−CO−CHX3
Dbutan-2-one
Answer: B, D
Propanal is an aldehyde and butan-2-one is a methyl ketone, so both add bisulphite. Acetophenone and benzophenone are conjugated and sterically hindered by phenyl groups, so they give no appreciable adduct.