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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3o1101

Select the correct statement(s) about the reaction of Grignard reagents with carbonyl compounds followed by acid hydrolysis.

  1. AAn ester with excess reagent gives a tertiary alcohol in which two of the alkyl groups come from the Grignard reagent.
  2. BAn aldehyde other than formaldehyde gives a secondary alcohol.
  3. CFormaldehyde gives a primary alcohol.
  4. DA ketone gives a secondary alcohol.

Answer: A, B, C

gives (primary), and any other aldehyde gives (secondary). An ester adds twice, so the tertiary carbinol carbon carries two identical groups from the Grignard reagent. A ketone gives a tertiary alcohol, not a secondary one.
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