JEE Advanced levelOne or more correct optionsDifficulty 3 of 3o1102
Under the usual laboratory conditions, which of the following reagents convert a ketone RX2C=O into the corresponding secondary alcohol RX2CH−OH?
AZn−Hg and conc. HCl
BLiAlHX4 in dry ether, then HX3OX+
CNaBHX4 in ethanol
DHX2 with Ni catalyst, heat under pressure
Answer: B, C, D
Hydride donors (NaBHX4, LiAlHX4) and catalytic hydrogenation reduce C=O to CH−OH. Clemmensen conditions (Zn−Hg/HCl) reduce the carbonyl all the way to CHX2.