JEE Main levelSingle correct optionDifficulty 2 of 3nc008
Propanone is treated with NHX3 and HX2/Ni (reductive amination). The product is:
Apropan-1-amine, CHX3CHX2CHX2NHX2
Bpropan-2-ol
CN-methylethanamine
Dpropan-2-amine, (CHX3)X2CHNHX2
Answer: D
Ammonia condenses with the ketone to give an imine (CHX3)X2C=NH, which is hydrogenated over Ni to the amine. The nitrogen is attached to the former carbonyl carbon, which is the middle carbon of the chain, giving propan-2-amine.