JEE Advanced levelSingle correct optionDifficulty 3 of 3mc196
50.0mL of 0.200MBaClX2 is mixed with 100.0mL of 0.150MNaX2SOX4. Assuming complete precipitation of BaSOX4 and additive volumes, the mass of precipitate and the final [SOX4X2−] are (Ba = 137, S = 32, O = 16)
A3.49g and 0M
B2.33g and 0.050M
C2.33g and 0.0333M
D2.33g and 0.100M
Answer: C
n(Ba2+) = 0.0500 x 0.200 = 0.0100 mol; n(SO4 2-) = 0.100 x 0.150 = 0.0150 mol, so Ba2+ is limiting. BaSO4 = 0.0100 x 233 = 2.33 g. Sulfate left = 0.0050 mol in 0.150 L, i.e. 0.0333 M.