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JEE Advanced levelSingle correct optionDifficulty 3 of 3mc196

of is mixed with of . Assuming complete precipitation of and additive volumes, the mass of precipitate and the final are (Ba = 137, S = 32, O = 16)

  1. A and
  2. B and
  3. C and
  4. D and

Answer: C

n(Ba2+) = 0.0500 x 0.200 = 0.0100 mol; n(SO4 2-) = 0.100 x 0.150 = 0.0150 mol, so Ba2+ is limiting. BaSO4 = 0.0100 x 233 = 2.33 g. Sulfate left = 0.0050 mol in 0.150 L, i.e. 0.0333 M.
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