JEE Main levelSingle correct optionDifficulty 2 of 3mc170
Complete combustion of 0.74g of an organic compound containing only C, H and O gives 1.76g of COX2 and 0.90g of HX2O. The empirical formula is (C = 12, H = 1, O = 16)
ACX4HX10O
BCX2HX5O
CCX4HX8O
DCX4HX10OX2
Answer: A
Mass of C = 1.76 x 12/44 = 0.48 g; mass of H = 0.90 x 2/18 = 0.10 g; mass of O = 0.74 - 0.48 - 0.10 = 0.16 g. Moles: C 0.04, H 0.10, O 0.01, ratio 4 : 10 : 1. Empirical formula is C4H10O.