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Empirical and molecular formula, percentage composition
JEE Main level
Single correct option
Difficulty 2 of 3
mc173
A hydrocarbon contains
92.3%
carbon and
7.7%
hydrogen by mass and its vapour density is
39
. Its molecular formula is (C = 12, H = 1)
A
C
X
2
H
X
2
B
C
X
6
H
X
6
C
C
X
4
H
X
4
D
C
X
8
H
X
8
Answer: B
Mole ratio C : H = 7.69 : 7.70 = 1 : 1, so the empirical formula is CH (mass 13). Molar mass = 2 x 39 = 78. n = 78/13 = 6, so the formula is C6H6.
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