JEE Advanced levelSingle correct optionDifficulty 3 of 3mt103
At 1200 K the standard Gibbs energies (per mole of OX2, in kJ) are: 2C+OX22CO, −440; 2CO+OX22COX2, −360; and for the oxides of four metals formed as 2M+OX22MO: A, −300; B, −380; C, −420; D, −520. How many of these oxides can be reduced by carbon but not by CO?
A2
B3
C1
D0
Answer: A
An oxide is reduced if its formation value is less negative than that of the reductant couple. Carbon (−440) reduces A, B and C but not D. CO (−360) reduces only A. So B and C are reduced by carbon but not by CO: 2 oxides.