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JEE Advanced levelSingle correct optionDifficulty 3 of 3mt103

At 1200 K the standard Gibbs energies (per mole of , in ) are: , ; , ; and for the oxides of four metals formed as : A, ; B, ; C, ; D, . How many of these oxides can be reduced by carbon but not by ?

  1. A2
  2. B3
  3. C1
  4. D0

Answer: A

An oxide is reduced if its formation value is less negative than that of the reductant couple. Carbon () reduces A, B and C but not D. () reduces only A. So B and C are reduced by carbon but not by : 2 oxides.
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