JEE Advanced levelSingle correct optionDifficulty 3 of 3mt102
Assertion (A): Carbon cannot reduce MgO to magnesium at 1500 K.
Reason (R): At 1500 K the Ellingham line of 2Mg+OX22MgO lies below that of 2C+OX22CO, so the coupled ΔG∘ is positive.
Choose:
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
For carbon to reduce MgO the CO line must lie below the MgO line. At 1500 K the MgO line is lower (more negative), so MgO+CMg+CO has a positive ΔG∘ and A is true. R states exactly this, so it explains A.