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IUPAC Nomenclature and Structural Isomerism
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Counting structural isomers
JEE Advanced level
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Difficulty 3 of 3
nm216
Which of the following statements about dichloro derivatives (structural isomers, no stereoisomers) is/are correct?
A
Propane gives 5 dichloro isomers
B
n-Butane gives 6 dichloro isomers
C
2-Methylpropane gives 3 dichloro isomers
D
2,2-Dimethylpropane gives 3 dichloro isomers
Answer: B, C
Substituting each H pair by Cl and de-duplicating: propane 4, n-butane 6, 2-methylpropane 3, 2,2-dimethylpropane 2 (1,1- and 1,3-). Correct: B, C.
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