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IUPAC Nomenclature and Structural Isomerism
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Counting structural isomers
JEE Advanced level
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Difficulty 3 of 3
nm219
Which of the following statements about saturated open-chain aldehydes and ketones of formula
C
X
5
H
X
10
O
(structural isomers only) is/are correct?
A
There are 7 such compounds in total
B
Exactly 3 of them give a positive iodoform test
C
5 of them are aldehydes
D
3 of them are ketones
Answer: A, D
Aldehydes: 4; ketones: 3; total 7. Iodoform-positive: pentan-2-one and 3-methylbutan-2-one only (2). Correct: A, D.
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