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IUPAC Nomenclature and Structural Isomerism
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Counting structural isomers
JEE Advanced level
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Difficulty 3 of 3
nm217
Which of the following statements about aromatic (benzene ring containing) structural isomers is/are correct?
A
C
X
8
H
X
10
has 4 isomers
B
C
X
9
H
X
12
has 9 isomers
C
C
X
7
H
X
8
O
has 5 isomers
D
C
X
7
H
X
7
Cl
has 4 isomers
Answer: A, C, D
C8H10: ethylbenzene + 3 xylenes = 4. C9H12: 2 propylbenzenes + 3 ethyltoluenes + 3 trimethylbenzenes = 8. C7H8O: 3 cresols + benzyl alcohol + anisole = 5. C7H7Cl: 3 chlorotoluenes + benzyl chloride = 4. Correct: A, C, D.
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