JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ig217
10mL of a gaseous compound containing only C, H and O was burnt in 45mL of OX2 (excess). After cooling the volume was 35mL, and after KOH it was 15mL (pure OX2). The compound is known to have molar mass 46. Which statements are correct?
AThe compound has 2 carbon atoms per molecule
BThe volume of OX2 consumed is 30mL
CThe molecular formula is CX2HX6O
DThe compound contains 6 hydrogen atoms per molecule
Answer: A, B, C, D
COX2=35−15=20, so x=2 (A). OX2 used =45−15=30 (B). CX2HXyOXz+(2+4y−2z)OX2: 10(2+y/4−z/2)=30, so y/4−z/2=1. With M=46: 24+y+16z=46, y+16z=22. z=1 gives y=6 and 6/4−1/2=1, consistent. CX2HX6O, ethanol (C, D). All correct.