JEE Main levelSingle correct optionDifficulty 2 of 3eq066
The same quantity of a reductant is oxidised separately by KMnOX4 in strongly acidic, neutral and strongly alkaline (to MnOX4X2−) media. The ratio of the moles of KMnOX4 consumed (acidic : neutral : alkaline) is
A15 : 5 : 3
B1 : 3 : 5
C3 : 5 : 15
D5 : 3 : 1
Answer: C
n-factors are 5 (to MnX2+), 3 (to MnOX2) and 1 (to MnOX4X2−). For a fixed number of equivalents the moles of KMnO4 are proportional to 1/n: 1/5 : 1/3 : 1/1 = 3 : 5 : 15.