JEE Main levelSingle correct optionDifficulty 2 of 3eq062
In acidic KMnOX4 titrations, the number of moles of KMnOX4 needed for 1 mol of FeCX2OX4 : 1 mol of FeSOX4 : 1 mol of HX2CX2OX4 respectively is in the ratio
A2 : 1 : 1
B3 : 2 : 1
C3 : 1 : 2
D1 : 1 : 1
Answer: C
Moles of electrons lost per mole: FeCX2OX4 gives 1 (Fe) + 2 (oxalate) = 3; FeSOX4 gives 1; HX2CX2OX4 gives 2. Since each mole of KMnOX4 accepts 5 electrons the mole ratio of permanganate is 3 : 1 : 2.