JEE Main levelSingle correct optionDifficulty 2 of 3eq060
20.0mL of an oxalic acid solution needs 22.4mL of 0.0200MKMnOX4 in hot dilute HX2SOX4 (HX2CX2OX4 oxidised to COX2). The molarity of the oxalic acid is
A0.112 M
B0.056 M
C0.0224 M
D0.028 M
Answer: B
2 MnO4- + 5 H2C2O4: mol oxalic acid = 2.5 x mol KMnO4 = 2.5 x (22.4/1000 x 0.0200) = 1.120e-03 mol. Molarity = 1.120e-03/0.0200 = 0.056 M.