JEE Advanced levelOne or more correct optionsDifficulty 3 of 3eq018
NaX2HPOX4 (molar mass 142gmol−1) reacts with both acids and bases. Select the correct statement(s).
AWith HCl forming NaHX2POX4, n=1 and equivalent mass =142
BWith excess HCl forming HX3POX4, n=2 and equivalent mass =71
CWith NaOH forming NaX3POX4, n=1 and equivalent mass =142
DWith NaOH forming NaX3POX4, n=2 and equivalent mass =71
Answer: A, B, C
Count the protons gained or lost per formula unit. HPOX4X2−+HX+HX2POX4X− takes one (n=1, 142); going on to HX3POX4 takes two (n=2, 71). HPOX4X2−+OHX−POX4X3−+HX2O removes one proton, so n=1 and 142; option 4 is wrong.