JEE Advanced levelNumerical answerDifficulty 3 of 3eq016
100mL of a solution contains 0.100MHX3POX4 and 0.0500MNaHX2POX4. What volume of 0.500MNaOH converts all the phosphorus species completely to NaX3POX4? Answer in mL (nearest integer).
Numerical answer type, answer in mL, tolerance 0.5.
Answer: 80 mL
Moles: HX3POX4=0.0100 (n=3 for HX3POX4POX4X3−) and NaHX2POX4=0.00500 (n=2). Equivalents =0.0100×3+0.00500×2=0.040. NaOH (0.500 N) volume =0.040/0.500=0.080L=80mL.