JEE Advanced levelSingle correct optionDifficulty 3 of 3eq019
500mL of a solution containing 3.70gCa(OH)X2 (molar mass 74gmol−1) is mixed with 400mL of 0.150MHX2SOX4. Assume both are fully dissociated, volumes are additive, and ignore any precipitate. The pH of the mixture is closest to:
A1.95
B1.35
C1.00
D1.65
Answer: D
Equivalents of base =3.70/37=0.100; equivalents of acid =0.400×0.150×2=0.120. Excess acid =0.020 equivalent in 0.900L gives [HX+]=0.02222M. pH=−log(0.02222)=1.65.