JEE Advanced levelNumerical answerDifficulty 3 of 3eq015
An oleum sample is labelled 118%, meaning that 100g of oleum yields 118g of pure HX2SOX4 on adding the required amount of water. Calculate the volume of 1.00NNaOH needed to neutralise 1.00g of this oleum completely, in mL (two decimals; HX2SOX4=98gmol−1).
Numerical answer type, answer in mL, tolerance 0.05.
Answer: 24.08 mL
1.00g oleum gives 1.18gHX2SOX4 after hydration. Equivalent mass of HX2SOX4=98/2=49, so equivalents =1.18/49=0.02408. For 1.00NNaOH, volume =24.08mL.