JEE Main levelOne or more correct optionsDifficulty 2 of 3eq012
17.1g of AlX2(SOX4)X3 (molar mass 342gmol−1) is completely precipitated as BaSOX4 by BaClX2 solution (treat BaClX2 as having n=2). Select the correct statement(s).
AThe n-factor of AlX2(SOX4)X3 in this reaction is 6
BIts equivalent mass is 57gmol−1
CThe sample is 0.30 equivalent
D600mL of 0.50MBaClX2 is required
Answer: A, B, C
Three SOX4X2− ions each carry 2 charges, so n=6 and equivalent mass =342/6=57. Equivalents =17.1/57=0.30. A 0.50MBaClX2 solution is 1.0N, so volume =0.30/1.0=0.30L=300mL, hence option 4 (600 mL) is wrong.