JEE Advanced levelSingle correct optionDifficulty 3 of 3df147
Consider the aqueous high-spin MX2+ ions of the 3d series from TiX2+ to ZnX2+ (nine ions). The number of these ions whose spin-only magnetic moment exceeds 4 BM is:
A4
B5
C2
D3
Answer: D
Unpaired electrons are TiX2+ 2, VX2+ 3, CrX2+ 4, MnX2+ 5, FeX2+ 4, CoX2+ 3, NiX2+ 2, CuX2+ 1, ZnX2+ 0. Moments above 4 BM need n≥4 (4.90, 5.92, 4.90), so only CrX2+, MnX2+ and FeX2+ qualify: 3.