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JEE Advanced levelSingle correct optionDifficulty 3 of 3df039

Zn has a much lower enthalpy of atomisation than V. The correct explanation is

  1. ABoth use only the two 4s electrons, but V has a larger atomic number
  2. BZn has more electrons and therefore stronger metallic bonding
  3. CV has 3 unpaired 3d electrons that take part in metallic bonding along with the 4s electrons, while the shell of Zn does not
  4. DZn uses its filled 3d electrons for strong bonding but V does not

Answer: C

V is and can use its unpaired electrons in addition to in metallic bonding, giving a high enthalpy of atomisation. Zn is with no unpaired d electrons, so only the pair contributes and the bonding is weak. This is why Zn also has a low melting point.
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