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JEE Advanced levelSingle correct optionDifficulty 3 of 3df038

Data in kJ/mol: for Cu, enthalpy of atomisation 340, , hydration enthalpy of ; for Zn, enthalpy of atomisation 130, , hydration enthalpy of . Which conclusion about is correct?

  1. AThe net energy for is for Cu and for Zn, so Cu is far less able to form and its is more positive
  2. BThe net energies are equal, so both have the same and any difference is due to entropy
  3. CThe net energy is for Cu and for Zn, so Cu has the more negative
  4. DHydration enthalpy alone decides , so Zn with the less negative value is more positive

Answer: A

Net energy = atomisation + ionisation + hydration. Cu: ; Zn: kJ/mol. A larger positive net value means oxidation to is less favourable, so Cu has the positive (+0.34 V) and Zn the negative one ( V).
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