Answer: A
Net energy = atomisation + ionisation + hydration. Cu: 340+2700−2120=920; Zn: 130+2640−2050=720 kJ/mol. A larger positive net value means oxidation to MX2+(aq) is less favourable, so Cu has the positive E∘ (+0.34 V) and Zn the negative one (−0.76 V).