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JEE Advanced levelSingle correct optionDifficulty 3 of 3df037

In weakly alkaline medium oxidises to and is itself reduced to . The mass of (molar mass ) required to oxidise mol of KI in this medium is

  1. A
  2. B
  3. C
  4. D

Answer: D

Mn changes from +7 to +4 (3 electrons per ) while I changes from to +5 (6 electrons), so 2 mol per mol : (balanced in atoms and charge). Moles = , mass = . The 9.48 g option wrongly uses the acidic 5-electron change.
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