NEET levelSingle correct optionDifficulty 1 of 3cc168
Assume [Ni(CN)X4]X2− is square planar because CNX− is a strong-field ligand. Its hybridisation and magnetic behaviour are:
Adsp2, paramagnetic
Bsp3, paramagnetic
Csp3, diamagnetic
Ddsp2, diamagnetic
Answer: D
NiX2+ is 3d8. The strong-field CNX− pairs the electrons in four 3d orbitals, freeing one 3d orbital. This 3d, the 4s and two 4p orbitals give dsp2 (square planar). No unpaired electrons remain, so the complex is diamagnetic.