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Thermodynamics of equilibrium: van't Hoff equation
NEET level
Single correct option
Difficulty 1 of 3
ce120
Use
R
=
8.314
J
mo
l
−
1
K
−
1
and
ln
10
=
2.303
. For a reaction with
K
=
1.0
×
1
0
3
at
298
K
,
Δ
G
∘
is closest to
A
+
17.1
kJ
mo
l
−
1
B
−
7.43
kJ
mo
l
−
1
C
−
1.71
kJ
mo
l
−
1
D
−
17.1
kJ
mo
l
−
1
Answer: D
Δ
G
∘
=
−
RT
ln
K
=
−
(
8.314
)
(
298
)
(
2.303
×
3
)
/1000
=
−
17.1
kJ
mo
l
−
1
. Using
lo
g
10
K
instead of
ln
K
would give
−
7.43
, and a positive sign is wrong because
K
>
1
.
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